Just wanted to settle this fact once and for all... well, in my mind.
Apparently,
The blue color of the sky is due to Rayleigh scattering. As light moves through the atmosphere, most of the longer wavelengths pass straight through. Little of the red, orange and yellow light is affected by the air.
However, much of the shorter wavelength light is absorbed by the gas molecules. The absorbed blue light is then radiated in different directions. It gets scattered all around the sky. Whichever direction you look, some of this scattered blue light reaches you. Since you see the blue light from everywhere overhead, the sky looks blue.
and...
As the sun begins to set, the light must travel farther through the atmosphere before it gets to you. More of the light is reflected and scattered. As less reaches you directly, the sun appears less bright. The color of the sun itself appears to change, first to orange and then to red. This is because even more of the short wavelength blues and greens are now scattered. Only the longer wavelengths are left in the direct beam that reaches your eyes.
